Webisopropylidene-N’-2-nitrobenzenesulfonyl hydrazine (IPNBSH), facilitated the reductive transposition of allylic carbonates with high regioselectivity and good to excellent yield. The reaction proceeded under mild conditions and was highly chemoselective. [Ir(COD)Cl] WebIPNBSH is further used for the reduction of vinyl epoxides to afford the corresponding homoallylic alcohols. 5-b Use of enantioenriched substrates did not lead to loss of …
N-Isopropylidene-N‘-2-nitrobenzenesulfonyl Hydrazine, a Reagent …
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N-Isopropylidene-N‘-2-nitrobenzenesulfonyl Hydrazine, a …
WebJan 1, 2012 · We recognized the utility of IPNBSH for generation of monoalkyl diazenes under basic reaction conditions. 5a These observations prompted our development of … WebJan 1, 2024 · However, the replacement of NBSH with IPNBSH was found to be also effective but gave a lower yield (entry 7). Unexpectedly, a profound yield improvement was observed by simply increasing the loading of Mitsunobu reagents (entries 8 and 9). Thus, with 2.0 equiv. of PPh 3 and DEAD, a good yield of 73% was obtained (entry 10). However, … WebJan 3, 2010 · 概要. N -isopropylidene- N ‘-2-nitrobenzenesulfonyl hydrazine( IPNBSH )を光延反応条件下にアルコールと反応させ、引き続き加水分解を行うことで、穏和な条件下 … dylan memphis blues